INFLUENCE OF THE MULTIPLICITY OF ULTRADISPERSE POLYTETRAFLUOROETHYLENE APPLICATION ON THE WETTABILITY OF PEO COATINGS ON TITANIUM

10.25712/ASTU.1811-1416.2026.03.002

Authors

DOI:

https://doi.org/10.25712/ASTU.1811-1416.2026.03.002

Keywords:

plasma electrolytic oxidation, titanium VT1-0, superdispersed polytetrafluoroethylene, wettability, composite coatings, hydrophobicity, surface energy, contact angle hysteresis, spraying method

Abstract

The paper studies composite coatings formed on commercially pure titanium grade VT1-0 by plasma electrolytic oxidation followed by the application of superdispersed polytetrafluoroethylene (SPTFE) by spraying and heat treatment. The relevance of the work is determined by the need to create hydrophobic protective coatings for metals operated in aggressive environments. The effect of the applied SPTFE suspension amount (1, 2 or 3 spraying cycles) on the morphology, wettability and surface energy of the composite coatings is determined. It is established that a single application of SPTFE provides uniform filling of pores without defects, a contact angle of 131.3±0.6° and a minimum wetting hysteresis (39.0±0.5°). The surface energy of the coating obtained with a single polymer application is 12.78±0.57 mJ/m², which is typical for hydrophobic fluoropolymer materials. Two or three applications lead to increased internal stress, crack formation, polymer film delamination, and a decrease in hydrophobicity. These results can be used in the development of protective hydrophobic coatings for titanium components operating in corrosive environments.

Author Biographies

Evgeniy Belov, Institute of Chemistry FEB RAS

junior researcher of the Institute of Chemistry, FEB RAS.

Sergey Suchkov, Institute of Chemistry FEB RAS

engineer of the Institute of Chemistry, FEB RAS.

Igor Imshinetsky, Institute of Chemistry FEB RAS

PhD of Chemical Sciences, Senior Researcher Officer of the Institute of Chemistry, FEB RAS.

Konstantine Nadaraia, Institute of Chemistry FEB RAS

PhD of Chemical Sciences, Senior Researcher Officer of the Institute of Chemistry, FEB RAS.

Dmitry Mashtalyar, Institute of Chemistry FEB RAS

Doctor of Chemical Sciences, Head of the Laboratory of composite coatings for biomedical applications of Institute of Chemistry, FEB RAS.

Published

2026-09-29

How to Cite

Belov Е., Suchkov С., Imshinetsky И., Nadaraia К., & Mashtalyar Д. (2026). INFLUENCE OF THE MULTIPLICITY OF ULTRADISPERSE POLYTETRAFLUOROETHYLENE APPLICATION ON THE WETTABILITY OF PEO COATINGS ON TITANIUM: 10.25712/ASTU.1811-1416.2026.03.002. Fundamental’nye Problemy Sovremennogo Materialovedenia / Basic Problems of Material Science, 23(3), 295–303. https://doi.org/10.25712/ASTU.1811-1416.2026.03.002

Issue

Section

SECTION 1. CONDENSED MATTER PHYSICS