FILLING OF THE ULTRA-HIGH MOLECULAR WEIGHT POLYETHLENE WITH SYNTHETIC WOLLASTONITE OBTAINED FROM VARIOUS TYPES OF BY-PRODUCTS
WTMALC
DOI:
https://doi.org/10.25712/ASTU.2072-8921.2025.02.026Keywords:
ultra-high molecular weight polyethylene, wollastonite, borogypsum, rice husk ash, mechanical and antifriction propertiesAbstract
The work presents a comparative analysis of the influence of wollastonite on the mechanical and tribological properties of ultra-high molecular weight polyethylene (UHMWPE). The relevance of the work is discussed by obtaining fundamentally new data on the modification of UHMWPE and the development of a new composition of polymer composite materials. The polymer matrix of UHMWPE in this work is characterized by an average molecular weight and an average particle size, which are characterized by high strength and self-lubricating properties. However, this polymer matrix is characterized by low wear resistance, so synthetic wollastonite is used for its modification and reinforcement. It is rational to synthesize this calcium silicate on the basis of rice husk ash and waste from boric acid production (borogypsum). Wollastonite obtained from rice husk was used to modify ultra-high molecular weight polyethylene (UHMWPE) with a high molecular weight of 9 million g/mol. Wollastonite from borogypsum was used to modify another UHMWPE sample with a molecular weight of 5 million g/mol. It was found that wollastonite obtained from boric acid waste is more effective in terms of improving the deformation and strength characteristics of UHMWPE and increasing its elastic modulus. Thus, the strength of composites increases by 27%, the elastic modulus by 50%, and the relative elongation by 18%, while wear resistance increases threefold. Wollastonite obtained from rice husk waste has proven itself to be a promising material for imparting antifriction properties to UHMWPE, such as a lower friction coefficient and minimum mass wear rate. It has been shown that this type of wollastonite reduces the rate of mass wear rate by 36% and the friction coefficient by 29% compared to the initial polymer.
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Copyright (c) 2025 Sakhayana N. Danilova, Ekaterina S. Yamaleeva, Elena M. Gotlib, Sofia B. Yarusova, Pavel S. Gordienko, Aitalina A. Okhlopkova, Lyubov N. Ivanova
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