REVIEW OF PHYSICO-MECHANICAL PROPERTIES OF BINDERS BASED ON VINYL ESTER RESINS
LIGAJI
DOI:
https://doi.org/10.25712/ASTU.2072-8921.2024.04.034Abstract
Unsaturated polyester resins are one of the essential binding materials in the production of composites. In spite of the fact that a slight decrease in the volume of their use is observed, polyester resins still maintain their leadership as the main binding component, both in the global production of composites and in the market of the Russian Federation. In this review we have analyzed scientific and technical literature on nanomodification and obtaining of hybrid resins on the basis of blending thermosetting resins. It is established, modification of vinylester resin with nanofillers of different nature of origin depends on the methods of their introduction and their combination. introduction and their combination, also on chemical properties of nanoparticle surface. Optimal indices of tensile strength, elastic modulus, hardness, thermal stability and UV-aging stability of nanocomposites in resin are reached when nanofillers are added in the range of 0.08-0.50 wt.%. The favorable interfacial interaction between nanofiller and matrix by means of covalent cross-linking reduced the interfacial surface defects of the composite material. Thus, the synergistic reinforcing effect gives reason to expect a promising future in obtaining high-performance materials on the based on modified vinyl ester resin.
The specific features of obtaining mixed resins, structures and physical and mechanical properties of composites based on them have been investigated. It is revealed that the developed interpenetrating polymer network formed as a result of oligomer mixing led to the improvement of hybrid composite properties in tension, bending and interlaminar shear compared to the original composites.
The results of research of the last promising reactive additives for thermosetting resins on the basis of organophosphorus compounds are also given, which contribute to the reduction of flammability of composites of various purposes from them without significant reduction of their heat resistance and strength properties
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